Large size growth of Zinc(tris) thiourea sulphate (ZTS) crystals has been successfully done through slow solvent evaporation technique in presence of l-Ascorbic acid (LAA). The possibility of any extra phase due to presence of LAA was ruled out through structural analysis. The deviation in lattice parameters and shift in peaks position indicates the interaction of LAA with ZTS. https://www.hindigyanvishv.com/hot-find-Facia-Installation-Kit-Suits-Holden-Commodore-VE-Series-2-FP9550BK-Black-top-mega/